ChemistryGeneral Chemistry

Predicting Precipitation: ALEKS Answer

Only potassium sulfide with lead(II) nitrate forms a precipitate, PbS. The barium nitrate/acetate and iron(II) chloride/nickel(II) sulfate pairs remain soluble.

Question

Predicting precipitationComplete the table below by deciding whether a precipitate forms when aqueous solutions A and B are mixed. If a precipitate forms, enter its empirical formula in the last column.1. Potassium sulfide + lead(II) nitrate2. Barium nitrate + sodium acetate3. Iron(II) chloride + nickel(II) sulfateFor each row, state Yes or No and, when Yes, give the precipitate's empirical formula.

Answers

Solution ASolution BPrecipitate?Empirical formula
Potassium sulfideLead(II) nitrateYesPbS\mathrm{PbS}
Barium nitrateSodium acetateNo
Iron(II) chlorideNickel(II) sulfateNo

1. Potassium sulfide and lead(II) nitrate

Exchanging ions produces lead(II) sulfide and potassium nitrate. Lead(II) sulfide is insoluble under the standard solubility guidelines:

Pb2+(aq)+S2(aq)PbS(s).\mathrm{Pb^{2+}(aq)+S^{2-}(aq)\rightarrow PbS(s)}.

Therefore a precipitate forms, and its empirical formula is PbS\mathrm{PbS}.

2. Barium nitrate and sodium acetate

The possible products are barium acetate and sodium nitrate. Acetate salts and nitrate salts are soluble under the standard guidelines, so no precipitate is predicted.

3. Iron(II) chloride and nickel(II) sulfate

The possible products are iron(II) sulfate and nickel(II) chloride. Neither is an insoluble exception in the standard sulfate and chloride rules, so no precipitate is predicted.

Evidence boundary

The predictions apply to the three aqueous pairs in the locked question version and use the standard qualitative solubility guidelines expected for introductory chemistry. They do not model unusual concentrations, temperature-dependent solubility, complex-ion formation, or kinetic effects not specified in the prompt.

Sources

These references support the concepts and methods used in the explanation above.

Predicting Precipitation ALEKS Answer | Verla