ChemistryGeneral Chemistry

How to Calculate Empirical Formula from P/O and K/H/P/O Percentages

Convert two complete percent-composition datasets to mole ratios, giving P₂O₅ and KH₂PO₄ with reverse checks.

Question

Determine the empirical formulas for compounds with the following percent compositions:

(a) 43.6% phosphorus and 56.4% oxygen (b) 28.7% K, 1.5% H, 22.8% P, and 47.0% O

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Evidence boundary

The percentages and two-part scope follow OpenStax Chemistry 2e Exercise 38. The 100 g basis is a calculation convenience, not an experimental sample. Atomic masses are rounded working values; small noninteger ratios come from the precision of the supplied composition. No molecular molar mass is given.